Thorin (chemistry)

Thorin (chemistry)
Names

Preferred IUPAC name Disodium 3-hydroxy-4-[(2-arsonophenyl)diazenyl]naphthalene-2,7-disulfonate
Systematic IUPAC name Disodium 4-[2-(2-arsonophenyl)hydrazin-1-ylidene]-3-oxo-3,4-dihydronaphthalene-2,7-disulfonate
Other names Disodium 4-[2-(2-arsonophenyl)hydrazin-1-ylidene]-3-oxonaphthalene-2,7-disulfonate 2-(3,6-Disulfo-2-hydroxy-1-naphthylazo)benzenearsonic acid disodium salt Thoron Thoronol
Identifiers
CAS Number	3688-92-4 (4E)-4-hydrazin-1-ylidene^N
3D model (Jmol)	Interactive image Interactive image
Beilstein Reference	2957648
ChemSpider	5020708 (4E)-4-hydrazin-1-ylidene^N 4895471^N
ECHA InfoCard	100.020.903
EC Number	222-993-1
PubChem	6364518 6537679 (4E)-4-hydrazin-1-ylidene
UN number	1557
InChI InChI=1S/C16H13AsN2O10S2.2Na/c20-16-14(31(27,28)29)8-9-7-10(30(24,25)26)5-6-11(9)15(16)19-18-13-4-2-1-3-12(13)17(21,22)23;;/h1-8,18H,(H2,21,22,23)(H,24,25,26)(H,27,28,29);;/q;2+1/p-2^N Key: ZQMPNLOZJUWHSA-UHFFFAOYSA-L^N Key: DCSRPHQBFSYJNN-GJLVVKPQBS InChI=1/C16H13AsN2O10S2.2Na/c20-16-14(31(27,28)29)8-9-7-10(30(24,25)26)5-6-11(9)15(16)19-18-13-4-2-1-3-12(13)17(21,22)23;;/h1-8,20H,(H2,21,22,23)(H,24,25,26)(H,27,28,29);;/q;2+1/p-2/b19-18+;;
SMILES [Na+].[Na+].O[As](O)(=O)c3ccccc3/N=N/c1c2ccc(cc2cc(c1O)S([O-])(=O)=O)S([O-])(=O)=O [Na+].[Na+].O[As](O)(=O)C1=CC=CC=C1NN=C1C(=O)C(=CC2=C1C=CC(=C2)S([O-])(=O)=O)S([O-])(=O)=O
Properties
Chemical formula	C₁₆H₁₁AsN₂O₁₀S₂
Molar mass	530.31 g·mol⁻¹
Appearance	Orange-yellow crystals
Melting point	300 °C (572 °F; 573 K)
Hazards
Main hazards	Toxic (T), Dangerous for the environment (N)
R-phrases	R23/25, R50/53
S-phrases	S20/21, S28, S45, S60, S61
NFPA 704	0 3 0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is ^YN ?)
Infobox references

Thorin (also called Thoron or Thoronol) is an indicator used in the determination of barium, beryllium, lithium, uranium and thorium compounds. Being a compound of arsenic, it is highly toxic.

References

Analytical Chemistry, 51, 2293 (1979).

External links

MSDS at Oxford University

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